1、1试题库三完成反应式题及解答1 2 3CH 3CH2CH=CH2 CH3CH2CH2CH2OH 4CH 3CH=CH2 5(CH 3)2C=CHCH2CH3 6CH 2=CHCH2OH 7CH 3CH2CH2CCH + HCl（过量） 8CH 3CH2CCH + HBr（过量） 9CH 3CH2CCCH 3 + KMnO4 10CH 3CH2CCCH 3 + H2O 11CH 2=CHCH= CH2 + CH2=CHCHO 12 13 14 15 16 17 18 19 20 (CH3)2C=CHCH3 HBrO3Zn,H2OClH2CHCH2OHOHH+H2SO4HgSO4CH3+HBr+C
2、l2+Cl2CH2CH3Br2+CH(CH3)2Cl2+ CH3O3H2OCH3H2OH2SO4B2H6H2O2O3H2CH=CH2CH3CH=CH2KMnO4CH3OCH=CH2+HBr221 22 23 24 25 26 2728 29 3031 32 33 34 35 36CH 2=CHCH2Cl CH2=CHCH2CN 37 (CH3)3CCl + NaOH 38 (CH3)2CHCH2CH2OH + HBr 39 40 41 +CH2Cl2AlCl3+CH3HNO3+KMnO4H+CH=CH2 Cl2C6H5CH2ClMg CO2 H+2OCH2=CHCH2Br+NaOC2H5CH=
3、CHBr2r AgNO3+Br2 KOH- CH2=CHCHOCH2ClClH2ONaH,H2OClCH3 OH-+SN2H2OCH3 OH-+Cl SN1BrKOH-H2OOH+HClZnCl2+HIOCH322OCH3FeBr2SO3HOHAlCl3CH3 H2SO4SO3/CH3Br EtONa342 43(CH 3)2CHBr + NaOC2H5 44 45 CH3COOH + CH3CH2CHO46 CH3COCH2CH2CH2CHO4748 49CH 3COCH2CH3 + H2N-OH 50 Cl3CCHO + H2O 51 52CH 3CH2CHO 53C 6H5COCH3 +
4、 C6H5MgBr 54 55 56(CH 3)3CCHO 57 58 59 60 61 62CH 2=CHCH2CH2COCH3 + HCl 63C 6H5CHO + CH3COCH3 64 65 66 +HIOC3CH3CH2CH2CH2CHCH3OHKMnO4H-HIO4HIO4CH3OH+Br2CH3CH2CH2CHCH2CH3OH H2SO4CHOH3C +KMnO4NaOHH2OH+OH2NHC6H5NaOHO+(CH3)2C(H2OH)2HCl+ONa2CrO7H+KMnO4CHOCH3OCl2H2OOH-,CH3O Cl2+ H+H2OH+CH3COCHCO2C2H5CH3 O
5、H-, ,CH3COCHCO2CH3CH2CO2CH3 NaOHCH3CH2CHOHOH +OH2NOH467 68 69 70 71 72 73 74 75 76 77 78 79 80HOCH 2CH2COOH 81NCCH 2CH2CN + H2O 82 83CH 3COCl + 84 85CH 3CH2COO C2H5 H+CO2CH3COCH3 HO2CH2COCOH3CH3 H2ONaOCH3CH2CHCOHCl -CH3CHCH2COHOHH2ONaO-OOH3CCH3CH2COHOHCH3 H2SO4CH3CH2COCO2HH2SO4CH3CHCOCO2HCH3 OHCHOH+
6、NaOOO,CH3CH2COHCl2+P-Na2Cr2O7H2O(CH3)2CHOH+ COClH3CLiAlH4NaOH H+CH2COHCH2COHBa(OH)2CH3AlCl3(CH3CO)2O+ OHNaOEt586CH 3COOC2H5 + CH3CH2CH2OH 87CH 3CH(COOH)2 88 89 90 91 92 93 94(C 2H5)3N + CH3CHBrCH3 95 (CH3)3NCH2CH2CH2CH3+Cl- + NaOH 96CH 3CH2COCl + 97 9899100 101 102 103 104 105 106+COHHCl+COHHOCH2CH2
7、OH2 COHLiAlH4+ OHHCOHCH2CH2COC2H5CH2CH2COC2H5NaOEtNCONH2OH-H3C NHCH3N(C2H5)2+HNO2O CHOH3C CH3SCH3H2O230%HAc NKMnO4 / H +NaOC2H5CH2CH2COC2H5CH2CH2COC2H5 CH3C2Br NaOH / H2O + / 2 H + / H2O CH2CH2CH2CNO H +CH3CH2CHOOH- NaBH4OHCN H2OH+CHO+HS(CH2)3SHHClCH3CH2OHNaBrH2SO4/Mg/ CH3CHOH2O? ? ?Na2Cr2O7HOCH2CH2
8、OH6107 108 109110 111 112 113 114 115 116 117118 119 120 121 122 123 124 125C6H5CHOCH3CH2CH2CHO+ OH-H2S+O1:1OH2/PdAl2O3? KMnO4OH- ?CH3COCH3CH3CH2CH2CHOH2N+(CH3)2CHCH2COHBr2P+CCOOOH2OH+OCH3HNO3H2SO4NH2/PtO+HCNCH2CH2NCH2CH3Me2+ CH3CH2CH2CHO+NaHSO3 ? ?Na2CO3+COBrH2OCH2CONH2 Cl2NaOH+OCH3H2SO4HNO3CH3CHO+
9、CH3CH2OHHCl(CH3CH2)3NCH2CH2COCH3OH+ -NCOHCOHCO2-CHOBr Zn-HgHClCOHCOH7126127 128129 130131132133134 135136 137 138 139 140 141142(CH3CH2CO)2O+ NH2CH3(CH2)4COClNaOHCl2C6H5COCH3H2NHCONH2ClH2CH2NMe2OHCH2CH3+ - NCOHSOCl2 CH3AlCl3CHOHCHOHNHCH3H2SO4HNO3Cl COCl NH3 NaOHBr23CHOCH2OHC6H5NH2C6H5CH2ClMg CO2H2O
10、SOCl2? ? ?H3C NHCOCH3HNO3+ HOAc(CH3)2CHCHCH3OHN(CH3)3+ -SCOCH3HNO3H2SO4COHCOHCH3(CH2)4COClNH3?Na OHCl2+ ?H2OCH2ClCCH2ClOHCN? ? ?NaCN H2O ?NH2CH3 SO2Cl+ ? ?NaOH8143144145146 147148149150151152153154155156157158159COH ?H2SO4HNO3NH2OH+(CH3CO)2OOHCH2COHCH2COHCH2COH ? AlCl3 ?Zn-HgCl ? AlCl3SOCl2 ?NH2 5HC
11、lNaO2+ OH- ?OHAg(NH3)2OH-CHOHO +COHPCl5CHO+H2NHCNH2HOAcOphCH2CH-NMe2CH3O+- +CH2SHCHSHCH2SHHgONKMnO4H+CHOCH3CHO+ OH-OCH3MgIH3O+ ? H2SO4 ? B2H6H2O2 ? CrO3 ?CH3CH2CH2CH2SHHNO3CH3CH2CH3O+O2N NHNH2NO2 HOAcCH2CH3 ?HNO3CF3 ?H2SO4HNO39160161162163164165166167168169170171172173174175176177HOCH2CH2CHOHCN?H3O+
12、 ?CH33 KMnO4H+ ? P2O5 ?C3? CH3NO2FeHCl ?(CH3CO)2O? H2SO4N3 ?H3O+?CH3CH-CHCH3CH3Cl KOH O3 H2OZn +CH2=CH-CH=CH2+ 180CF3-CF=CF2ZnCl2 CH2Cl+ 60+CH3CH2CH-CCHCH3 +H2OH2SO4HgSO4CH3CH2OCHCH3CH3 +HI() +CH3CH3CH3 HNO3CH2OH+PBr3 MgCH3CCH+CH2OCl4NBS+HBrCH3CH-CH-C-H3OHOHOHCH3 HIO42CHCH2CH2CH2CH3Na CH3I Na? ? ?CH
13、3CCHNa CH3CH2Br ? H2Pd / BaSO4 ?CH3CCH3 NaH2+CH2=CH-CH=CH2+CH=CHCNCl2HCHOZn Cl2HCl Fe? ?Na OHH2 ?CH3CH2=CH-CH=CH2+CH=CHCHO10178179180181182183184185186187188189 190 191 192 193 194 195H2COCHCH2CH3H2O HIO4?BrNaOHEt+ COClAlCl3CH=CHBrKCNCH2ClOCH2CH3 HIOO+CH3HIO3 H2OZn/CH3HBrCl2+FeCl3OOO+H2+ Ni80OO+CH=CHBrCl NaOC2H5CH3CH3CH3HBr+ OOOOCH3+HI
