1、12 饱和脂肪烃1完成下列反应式：答案： (1)(2)(3)(4)3 不饱和脂肪烃一完成下列反应：(3) + BrH(4) + Cl2 hvCH3CH2CH3 Br2(1) + hvCH3CCH3CH3Cl2CH3hv(2) +CH3CH2CH3 + Br2 CH3CHBrCH3hvCH3CCH3CH3CH3CH3CCH3CH2ClCH3Cl2+ hvBr+HBrCl Cl+Cl2 hvCH3HI+Cl3CHCH2CH32CHCH2HOClCH3CH3CC2CH2HBr+H2+Pd/BaSO4+HBr( 3)( 4)( 5)( 6)( 7) OOO+( 8)H2SO4CH3CH2C CH2CH
2、3+CH3CH2C CH2CH3HClH2O+(1)(2)2答：反应产物为：二、完成下列反应式1 (1)(2)CH2 H2OH2SO4C(CH3)22 H2O2CH3 HBr3 O3 Zn/H2OCH3CH2CH=CH24 (1)(2)CH2 H2OH2SO45 Br23006 H2OCl2 7 (1)(2)CH2 H2O2CH2CH OHB2H68 KMnO4OH9 H+KMnO4C2H5 C2H5CH=CH10 H3O+C6H5CO3H11 H+KMnO4C2H512 H2O2OsO413 CH2 H2O2OHB2H614 H2O2OHCH3 B2H6CH3CH2CCH3ClCH3（1）（
3、2）CH3CH2CCH3OSO3HCH3 CH3CH2CCH3OHCH3（3）ICH3（4）Cl3CCH2CH2Br（5）CH3CH2CHCH2ClOH （6）CH3CH=CHCH3（7）HCCCH2CHCH3Br （8）OOO315 (1)(2)O3(CH3)2CH Zn/H2OCH3CH16 H2OBr217 NBSCH318 CH2 H2OCl2C(CH3)2 19 CH3 Br2CCl420 (1)(2)O3Zn/H2OCH321 KMnO4OHHC2H5C C2H5HC22 H2O2CH3 B2H6 OH23 Br2CCl424 H2OCH3CH3 OsO4NaHSO325 CH2C
4、H HBrC6H5 ROOR26 (1)(2)O3CH2 Zn/H2OC2H5 CCH327 HIF3C CH=CH228 CH2 CH2H2O2OHB2H629 CH2 H+IClC(CH3)230 H2SO4H3O+CH3答案：1. 2. 3. CH3CH2CHO + HCHO 4. OHCH3C(CH3)2 BrCH3 OHCH35. 6. or 7. Br HOCl ClOH CH2CH2 CH2OH48. 9. 10 OHOH COOH2 CH2CH3 ()OHOHO11. 12. 13. COOHCOCH3 (CH2)3 OHOH CH2OH14. 15. 16. CH3OH (C
5、H3)2CHCHOCH3 CHOBrOH17. 18. 19. BrCH3 CH2ClC(CH3)2 OH BrCH3Br ()20. 21. 22. or CHOCOCH3 (CH2)3 OHHHOC2H5HC2H5() CH3OH CH3OH23. 24. 25. BrBr() CH3CH3OHOH CH2CH2C6H5 OH26. 27. 28. HC2H5 C COCH3 HO CH2CH2IF3C CH2 CH2HO OH29. 30. CH2(CH3)2CH ICl OSO3HCH3 OH CH3三、完成下列反应式1 Cl2CH2 CH2CH CHC2 H2SO4CH3CH2 CH
6、C HgSO43 CH CHCHCH3 OCH=CH2 CCCH OO4 NaCH2CH3 NH3 OsO4H2O2CH3CC 主5 CHCH3 Br2CCl4CH3CCCH6 H2主主LindlarCH3 CH3C C7 H2OH+CHC HgSO48 Na H2OH+CH2BrCHC HgSO459 H2OCH H2SO4CHCH3 CHC HgSO410 KMnO4CHKOHCH3CH2C11 CH2Cl CH2 +CHF C C Ag(NH3)212 OHCHB2H6H2O2CH3CH2C13Na INH3 CH3CHCH3C 主 H2Pt /Pb14 H2OCOOH KMnO4C2H
7、5 CH3CHB2H6C15 CH2CH2 CH HBrCHC (1mol)16 CH2C HBrCH3 CH=CH217 HClCHC6H5 CHCH=CH218 OHCH3 B2H6H2O2CH3CC19 O3C H2OCH3CH2 CH3C20 ClNaNH2 OHCH3 B2H6H2O2ClC答案： 1. 2. 3. ClCH2 CH2CHCl CHC COCH3CH3CH2 OCH3CCOO4. 5. 6. HHC C2H5CH3 C HOC2H5()OHCH3H H CHBrCH3 Br CH3CCCH HHCCH3 CCH37. 8. , OCH3C CH2 CHC CH2 CH
8、3CO9. 10. CH CH3COCH3 CH COOKCO2CH3CH211. 12. CH2 CCl CH2FC C Ag CHOCH2CH3CH213. , ,CNaCH3C CCH3CH3C HHCCH3 CCH3614. , 15. C2H5CH=CH2CH2OHC2H5OHCH CH2CHBr CHCH3 C16. 17. CH2C BrCH3 BrCHCH3 (主) CH2CCH3CHCH3 (主) CHC6H5 CHClCHCH318. 19. COCH3CH3CH2 COOHCH3CH2 CH3COOH20. CHC CH2CHO4 芳香烃一完成下列反应式：答案：CH3HN
9、O32S4（1） (CH3)CCH23KMnO4/H+（2） AlCl3CH32CH2l+（3） CH(3)2Cl2+光照（4） (CH3O)2 AlCl3+（5） CH23Cl2FeCl3+（6） CH22CH2OClAlCl3（8）CHOCH3OClAlC3+（7） 3N32S4（1）CH3NO2 H3C NO2+(CH3) 2H3KMnO4/H+（2） (CH3)3C COOH（3） AlC3CH32CH2l+ CH(CH3)2CH(3)2Cl2+光照（4） C(CH3)2Cl（5） (CH3O)2 AlCl3+ COCH3CH23Cl2FeCl3+（6） +CH2CH3Cl CH2CH
10、3ClCHOCH3OClAlC3+（7） CHOCOCH3CH22CH2OClAlCl3（8）O7二、完成下列反应式1 KMnO4C2H5H3C2(CH3)3CClCH3CH3 AlCl3103 H2SO4 Cl KMnO4H3C HNO34Br2 Cl2hvH3C Fe5 H2SO4606. CH2 ClCH3AlCl3 CO Zn-Hg主HCl7 COOHOHCH3 CH3HNO3(2 mol)8 H2SO4NO2NHHNO3CO9. H2SO4 KMnO4BrC2H5 HNO310. KMnO4(CH3)3C11. H2SO4HNO3COO12. Br2OCH3 FeCOCH3O13.
11、HCl(1)(2) H2SO4 KMnO4AlCl3 HNO3 主14 H2SO4CH2 HNO3O2 N15. CH2 ClCH2 AlCl3CO16. OHCH2CH2 (CH3)2C HF817 NO2Cl2OCH3 Fe18 H2SO4NO2CH3O HNO319 H2SO4Cl NHCOCH3 HNO320 H2SO4O2N HNO321 H2SO4 H+KMnO4HNO3 ,22 CH2 ClCH3AlCl3 COCO23Al3C22C2l24 + CH32CH22ClAlC310 KMnO425 CH2OClAl326+ C2 KMnO4CH2AlC3答案：1 ；2 ；3 ， ；
12、4 ，COHHOOCCH3CH3C(CH3)3 NO2ClCH3 NO2COOHClCH3Br；BrCH2Cl5 ；6 ， ；7 ；SO3H CH3CH2CO CH2 CH3CH2 NO2O2NOHCH38 ， ；9 ，NO2O2N NHCO COOHBr NO2COOHBr10. ；11. ， ；12.(CH3)3C COOH NO2O2N COO Br OCH3COCH3O913. ， ； 14. ； 15.NO2COOH O2N NO2CH2 O16. ；17. ；18. ；19. ；CH3CH3 NO2Cl OCH3 NO2CH3O Cl NHCOCH3NO220. ；21. ， ；2
13、2. ；NO2O2NNO2 O2NCOOCO CH2 CH3COCO23 ；24 ， ；25 ；CH(CH3)2 COOH O26 ， ；C2H5 COOH5 脂环烃一、完成下列反应式1 2+ CH3O + CH2Cl3 4CH3CCH22+ HBr + COEtt5 6CH3CCH22+ HCl CH3+ COH337 8. CH3+3 COH33 H3CH3C CH2CH3 Cl2+9 10. +OCH3 HBrH3CH3C CH2CH3+11 12. CH OHCH CH3KMnO4 CHC H+CH3CH3 KMnO41013. 14. H2SO4 H2O+CH3 + COCH3CH3
14、OC15. 16. +CO2CH3 CHO +17. 18. +COCO+ O19 20. +CH3 CH3 + COOCH3COOCH321. 22. NO2CH2+ hv答案：1. 答： 2. 答：COCH3 Cl3. 答： 4. 答：CHCH2CH3CH3Br COEtCOEt5. 答： 6. 答：ClCHCH2CH3CH3 COCH3CH3COCH37. 答： 8. 答： COCH3CH3CH3 COOCH3 C2H5Cl CCH2CHCH3ClCH39. 答： 10. 答：COCH3 CH3CH3CHCCH3CH3Br11. 答： 12. 答： CH3CHOHOHCHH3C CCH3OCH3COH13. 答： 14. 答： OHCHCH2CH3CH3 COCH3COCH315. 答： 16. 答： COCH3 CHO
