1、1有机化学 II 总复习（一）完成反应式解答H+2CH5CO OOC2H5C2H5HOCH=CHO OCOHHOC HOCOCOH OC6H5Na + 2CH2BrC6H5OCH2=C2+CO2a CH2BrBr H2OCBr+CH32C2OHBr2P OH-2CH32Cr C3H2COHCOHlPb(OAc)4, I2Cl RONaClHIOC2H5O H+C25OOOC2H5 OC2H5COlO2NHNNaOH2+ NC2N+CH3N2CH3O C3ONHC3OC2H5OOCH33 NaCH33 OOHC25NHLiAlH42ONH2H3O+LiAl4(1)(2)O CH2O22, Pd/
2、BaS4ClCl CHOClC2H5OH+CH3=H2C2OC25Na 3CH=C2H2C2OH+(CH2)1OC3OCH3Na (CH2)10OH25COl(CH32)CdO25CH23CH32l(CH3)2uLiethrCH32COH3+OC2H5MgBr+/2C2H2C2H5OH+/2OCN6H5MgBr CONaOC2H5CH2OC2H325 OOCH3+25O3CO2H5C25ONaCH2CO2H5OH+CO2H525C25ONa OH-2 2 OOH5C2OC25+CH32NO2CH2=CO3NaH3C3HC22CH3NOO+OCO2H525C6HNaOCOC2H5+CH2N(C2
3、5O)2C25ONa CHOC2H5N3+ H+NaCH3OHCO2H5ethr CH3OCHOCH32COC2H5LDA,THF CH32IC3H2CO25Li+ CH32COC2H52325ONaNCH2OC2H5 3O=PhNO25CH2CH3CH3O3(1)2COH+ ClH2OC2H5NaOH /2+ 3O C3OC2H5C3HOOClH2OC2H5KOC(H3)t Bu+ CO2H5+BrCH2OC2H5Zn/C6H+1.2. OH-/2+/1.2. CH=COHC2H5O(C2)4OC2H5NaOC2H5 (1)(2)NaOC2H5Br (1)2OH- /2+CO2H5 CO2H
4、5 OC2H5+ H3O+NH Cl2=CH2(1)2N OCH2=CH2NHOOK(s) PhCH2Br H2O-N-K+OO NOOCH2 CH2N2H3CNH2PhCBr2 /H3CPhNH2NHOOBr2/OHNH2CO-BrN2Zn/H H+NHBrBr Br Br2N NH24C6H5ON2P2O5C6H5N CH3ONa3CH2l CH2N= CH2NCOH3CO2HSCl2CH2N Ag2OHCHN2O CH2OH2O(1)CH2NOCH3O2N 2/Pt LiAl4C2NOC3H2N CH2N2CH3H2N2/PtOCH32NH2+NHC23NHC3HOCHO/+NCH3Om
5、anich reactionOCH2N2HNO2HClNH2OaNO2OCH3C2C(H3)2(H3) 50 CC=H(3) H(C3)250 CCH3 BrHD32CC3OCH3 DOCH332C C=H323HDCH32CN(3)O H3 CH32CH=2N(CH3)OC3H3+ CH33 N(CH3)2233H2O 20 CN(CH3)223O-3+ CH23CH35NHCH33IAg2OH NCH3CH3CH3+O- NCH3CH3CH3+NClCH3 ClHONaOH2 ClHON=C3CH325CH3OCH3 CH3OCH3CH325CO2H323. HCO2H3CH3O2( )
6、( )HCO2H323CH325 + C2H5CH3CH3+CH2NCH3OCOCH3+ NO3CH3+ONCH2=COH3 NOCH3OCHOC2H5 HOOC2H5 O2H5OCH=22 +OCH3CH3 CCH3OCOCH3 CH3OCOH33H36+SHCOHCl/Znl2SCH2l+COSBr2CH3O25 o OHSBrSH2SO45 C SSO3H+NNCH3IH NNHC3I-+(1)2NCH3CH3NaH2PhCOl NCH2OphCH3NH2SO4N3 NNO2 NO2+ H3O+CH3NC6H5Li OCHO NCH=ONCH2OLiCllNCH3ONa, ClNOH3NCH3RLi CH2=CNNCH2Li NCH22CH2NC2H5ONaNH2aNO2,HCluBr (25)23+OBrN CH2ONOCHONCH2OC2H53N4OC=CO2H5+NCH3 CH3ONaH2NCH=37+HOHCH2OC2PhNH23 HAcHOHCH=NphC2OCH3OC3CH3CH3O3 CH2O3OCH33 3O+ +OHCH2O3C3CH3OOHCH2O3C3CH3O3+HOH2C2Ag(NH3)2+ O-HOHC2OHH-CH2OCHOOHC2H OCHOCH2OHOHOH2 NaBH4 CH3OC3l
